Berichtigung: Acyloxybutadien-Fe(CO)3-Komplexe als enzymatisch aktivierbare, CO freisetzende Moleküle (ET-CORMs)
نویسندگان
چکیده
منابع مشابه
Quantum-CORMs: quantum dot sensitized CO releasing molecules.
The synthesis and photodecomposition behaviour of a family of CO releasing molecules (CORMs) based on [Mn(CO)3bpy] derivatives connected to a semiconductor Quantum Dot (QD) sensitizer is described here. Compared to the non-sensitized complexes, such systems show a 2 to 6-fold increase of the photodecomposition rate upon irradiation with visible light.
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A series of η(4)-acyloxycyclohexadiene-Fe(CO)(3) complexes was prepared and fully characterized by spectroscopic methods including single crystal X-ray diffraction. For this purpose a new synthetic access to differently acylated 1,3- and 1,5-dienol-Fe(CO)(3) complexes was developed. The enzymatically triggered CO release from these compounds was monitored (detection of CO through GC and/or by m...
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متن کاملDifferent design of enzyme-triggered CO-releasing molecules (ET-CORMs) reveals quantitative differences in biological activities in terms of toxicity and inflammation
Acyloxydiene-Fe(CO)3 complexes can act as enzyme-triggered CO-releasing molecules (ET-CORMs). Their biological activity strongly depends on the mother compound from which they are derived, i.e. cyclohexenone or cyclohexanedione, and on the position of the ester functionality they harbour. The present study addresses if the latter characteristic affects CO release, if cytotoxicity of ET-CORMs is...
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2011
ISSN: 0044-8249
DOI: 10.1002/ange.201190036